Using diffraction gratings to identify elements

What is a spectrograph?

A spectrograph takes light from a source and separates it by wavelength, so that the red light goes in one direction, the yellow light in another direction, the blue light in another direction, and so forth. There are two basic ways of dispersing light. You can pass it through a prism

or you can bounce it off (or pass it through) a diffraction grating

  Q:  Most astronomers these days use gratings, 
      not prisms.  Can you guess why?

The answer

You can read about the physics of diffraction gratings if you want to understand exactly how and why they work.

If you just attach a grating (or prism) to your telescope, so that light from all over the field of view strikes the grating (or prism), you will see a somewhat confusing combination of image and spectrum together:

Astronomers often place a slit over the focal plane of the telescope, centered on the object of interest.

Only light which passes through this slit will strike the grating (or prism), giving the spectrum a characteristic shape: vertical lines on a long, horizontal canvas.

Image by Maurice Gavin, from the wpo-amateur spectroscopy web site.

The basic types of spectrum

When we pass light from a source through a spectrgraph, we usually see one of three basic types of spectrum, depending on the nature of the source. German astronomer Gustav Kirchoff, working in the 1850s, figured out the reason for these different types of spectra. He explained the three basic types of spectra as coming from three different situations:

1. Solids, liquids, and dense gases emit light of all wavelengths, without any gaps. We call this a continuous spectrum.

   

   

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2. Thin gases emit light of only a few wavelengths. We call this an emission or bright line spectrum.

   

   

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3. If there is a source of light behind it, a thin gas will absorb light of the same wavelengths it emits. We call this an absorption or dark line spectrum.

   

   

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Using spectra to identify elements

Each element generates its own unique set of wavelengths of emission or absorption.

• Click to see a mirror image of the figure above

We can use these patterns like fingerprints to identify the material which is emitting or absorbing light.

• Photographs of spectra from emission tubes

The Challenge

1. Identify the element in each of the four lamps
2. What element dominates the spectrum of the fluorescent bulbs on the ceiling of this room?
3. There are several lamps in the room. Look carefully at the spectrum of each one.
   • What is the wavelength of the bright yellow line in helium's spectrum? Show your work.
   • What is the wavelength of the green line in mercury's spectrum? Show your work.
   • What are the wavelengths of all the lines you can see in the spectrum of hydrogen? Show your work.

For more information

• The sample slitless spectrum shown above comes from a paper describing the QUEST telescope
• The WPO-amateur spectroscopy page explains how spectra are acquired and analyzed.
• You can generate your own spectra with the MiniSpectroscopy Java Applet
• You can read a lot more about spectral analysis of light at Nick Strobel's Astronomy Note's on Spectra.
• Some examples of stellar spectra are given in a lecture on the chemical composition of stars.
• Examples of emission-line spectra of different elements

Copyright © Michael Richmond. This work is licensed under a Creative Commons License.